张程琨;王璇;何金兴;

• 1:齐鲁工业大学食品科学与工程学院

摘要(Abstract)：

分子印迹光子晶体技术因其较好的专一性,选择性,灵敏性以及响应性,目前被广泛应用于食品中有毒物的检测。本文介绍了分子印迹光子晶体技术的原理、合成方法以及在食品中痕量有毒物检测中的应用,其中对农药吡虫啉、莠去净、甲基膦酸的检测限达到10~(-13)g/mL、10~(-8)ng/mL、10~(-6)mol/L,对兽药氯霉素、17β-雌二醇的检测限达到1 ng/mL、1.5 ng/mL,对食品中三聚氰胺和双酚A的检测限达到10~(-5)mg/mL、10~(-10)mol/L,并对分子印迹光子晶体技术进行了展望。

关键词(KeyWords)： 分子印迹;光子晶体;检测

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金青年基金(31301470)

作者(Author): 张程琨;王璇;何金兴;

Email:

DOI: 10.16442/j.cnki.qlgydxxb.2017.03.006

参考文献(References)：

• [1]PAULING L.Antibody formation theory[J].J.Am Chem Soc.1940,62(3):2643.
• [2]WULFF G,SARHAN A,ZABROCKI K.Enzyme-analogue built polymers and their use for the resolution of racemates[J].Tetrahedron Letters.1973,14(44):4329-4332.
• [3]HUANG X P,Liu Y F.Study on molecular imprinting technology[J].Henan Chemical Industry.2011,28(9):29-32.
• [4]SCHIRMER C,MEISEL H.Synthesis of a molecularly imprinted Polymer for the selective solid-Phase extraction of chloramphenicol from honey[J].Journal of Chromatography A.2006,1132(1):325-328.
• [5]PAN M F,FANG G Z,LIU B,et al.Novel amperometric sensor using metolcarb-imprinted film as the recognition element on a gold electrode and its application[J].Analytica Chimica Acta.2011.690:175-181.
• [6]SERGEYEVA T A.,PILETSKY S A.,BROVKO A A.,et al.Selective recognition of atrazine by molecularly imprinted polymer membranes.Development of conductometric sensor for herbicides detection[J].Analytica Chimica Acta.1999,392:105-111.
• [7]YABLONOVITCH E.Inhibited spontaneous emission in solid-state physice and electronics[J].Physical Review Letters.1987,58:2059-2062.
• [8]JOHN S.Strong localization of photonics in certain disordered super lattices[J].Physical Review Letters.1987,58:2486-2489.
• [9]CREGAN R F,MANGAN B J,KNIGHT J C,et al.Single-mode photonic band gap guidance of light in air[J].Science.1999,285(5433):1537-1539.
• [10]NISHIMURA S,ABRAMS N L,BRADLEY A,et al.Standing wave enhancement of red absorbance and photocurrent in dyesensitized titanium dioxide photoelectrodes coupled to photonic crystals[J].Journal of the American Chemical Society.2003,125(20):6306-6310.
• [11]YE J Y,ISHIKAWA M.Enhancement of two-photon excited fluorescence using one-dimensional photonic crystals[J].Applied Physics Letters.1999,75(23):3605-3607.
• [12]JENNIFER I L C,GEORG F,SUNG Y C,et al.Slow photons in the fast lane in chemistry[J].Journal of Materials Chemistry.2008,18:369-373.
• [13]GAN D,LYON L A.Interfacial nonradiative energy transfer in responsive core-shell hydrogel nanoparticles[J].Journal of the American Chemical Society.2001,123(34):8203-8209.
• [14]VUKUSIC P,SAMBLES J.R,LAWRENCE C.R,et al.Structural colour:Now you see it—now you don't[J].NATURE.2001,410(6824):36.
• [15]BURNS M M,FOURNIER J M,GOLOVCHENKO J A.Optical matter:crystallization and binding in intense optical fields[J].Science.1990,249(4970):749-754.
• [16]LOPEZ C,VAZQUEZ L,MESEGUER F,et al.Photonic crystal made by close packing Si O2submicron spheres[J].Superlattices and Microstructures.1997,22(3):399-404.
• [17]KITAEY V,OZIN G A.Self-assembled surface patterns of binary colloidal crystals[J].Advanced Materials.2003,15(1):75-78.
• [18]JIANG P,BERTONE J.F,HWANG K.S,et al.Single-crystal colloidal multilayers of controlled thickness[J].Materials Chemistry.1999,11(8):2132-2140.
• [19]HU X B,AN Qi,LI G T,et al.Imprinted photonic polymers for chiral recognition[J].Angewandte Chemie.2006,118(48):8325-8328.
• [20]HATTON B,MISHCHENKO L,DAVIS S,et al.Assembly of largearea,highly ordered,crack-free inverse opal films[J].Proceedings of the National Academy of Sciences of the United States of America.2010,107(23):10354-10359.
• [21]WANG X,MU Z D,LIU R,et al.Molecular imprinted photonic crystal hydrogels for the rapid and label-free detection of imidacloprid[J].Food Chem.2013,141(4):3947-3953.
• [22]STOBER W,FINK A,BOHN E.Controlled growth of monodisperse silica spheres in the micron size range[J].Journal of Colloid and Interface Science.1968,26(1):62-69.
• [23]WU Z,TAO C A,LIN C X,et al.Molecular imprinting label-free colorimetric detection of trace atrazine in aqueous solution by using molecularly imprinted photonic polymers[J].Chemistry-A European Journal.2008,14:11358-11368.
• [24]LIU F,HUANG S Y,XUE F,et al.Detection of organophosphorus compounds using a molecularly imprinted photonic crystal[J].Biosensors and Bioelectronics.2012,32(1):273-277.
• [25]ZHOU C,WANG T,LIU J,et al.Molecularly imprinted photonic polymer as an optical sensor to detect chloramphenicol[J].The Analyst.2012,137(19):4469-4474.
• [26]WANG L Q,LIN F Y,YU L P.A molecularly imprinted photonic polymer sensor with high selectivity for tetracyclines analysis in food[J].Analyst.2012,137(15):3502-3509.
• [27]SAI N,WU Y T,SUN Z,et al.Molecular imprinted opal closestpacking photonic crystals for the detection of trace 17β-estradiol in aqueous solution[J].Talanta.2015,144:157-162.
• [28]YOU A M,CAO Y H,CAO G Q.Colorimetric sensing of melamine using colloidal magnetically assembled molecularly imprinted photonic crystals[J].RSC Advances.2016,6(87):83663-83667.
• [29]MAYES A G,MOSBACH K.Molecularly imprinted polymer beads-suspension polymerization using a liquid perfluorocarbon as the dispersing phase[J].Analytical Chemistry.1996,68(21):3769-3774.
• [30]GRIFFETE N,FREDERICH H,MATRE A,et al.Introduction of a planar defect in a molecularly imprinted photonic crystal sensor for the detection of bisphenol A[J].Journal of Colloid and Interface Science.2011,364(1):18-23.

文章评论(Comment)：